Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

现有军用光电装备快速智能化手段

近年来,人工智能技术在图像处理领域取得了突破性进展,使得目标识别和目标检测算法的性能得到大幅提高,也为军用光电装备智能化创造了有利条件。本文从算法、数据和计算能力等人工智能三要素入手,分析了快速实现军用光电装备智能化的有效途径及过程中可能面临的问题,指出:现有的技术理论基本满足装备升级需求,智能化过程中还应重点加强实时性算法的研究,提早对专用数据集的收集整理进行布局完善,采用低功耗高性能边缘计算设备为装备计算能力水平提升提供支撑等。同时,在工程化过程中仍存在部分实际问题,需根据装备进行个性化设计,以解决理论与应用之间的差距。最后,建议重点加强国产化水平与能力的提高,以实现关键技术自主可控。     

低频UWBSAR辐射校准模型

低频超宽带合成孔径雷达(Ultra Wide Band Synthetic Aperture Radar,UWBSAR)的辐射校准是系统研制和应用过程中必须面对的课题。低频UWBSAR的特点使得常规SAR辐射校准技术不再适用。充分考虑校准参数随频率和方位角的变化,给出适合该系统的辐射校准方法,得到低频UWBSAR图像辐射校准模型。利用该模型,对系统辐射校准误差进行了分析。     

舰艇武器布置问题的一种协同优化算法

针对舰艇武器布置问题的特点,提出了一种基于粒子群优化和分类器系统的协同优化算法,以粒子群优化进行优化计算,用分类器系统消除约束.计算实例表明,该算法能较好地实现优化计算,并能节省大量的计算时间.     

MILITARY EXPENDITURE AND ECONOMIC GROWTH IN DEVELOPING COUNTRIES: EVIDENCE FROM SYSTEM GMM ESTIMATES

The effect of military expenditure on economic growth in developing countries has been investigated by many empirical literatures. However, there is little consensus of that effect and the diversity seems to come from the use of different models and different estimators. This article applies the Augmented Solow Growth Model to examine the influence of military expenditure on economic growth for 35 developing countries over the period of 1975–2009. By using the system Generalized Method of Moments (GMM) estimators, empirical results indicate that defence has a negative and significant effect on economic growth in the sample countries.     

战时装备调配保障决策模型构建研究

分析了战时装备调配保障决策的特点,运用模糊聚类分析法对装备调配保障对象进行了分组和优先级排序,以此为基础,运用目标规划法构建了战时装备调配保障决策模型,最后,通过实例验证了模型的可行性和有效性．     

直升机反伏击行动对策研究

直升机反伏击行动,必须坚持先期感知战场态势、有效隐蔽飞行企图、建立安全的低空飞行走廊和力争先机制敌伏击的作战指导,采取预先侦察、多备航线、陆空协同和施计用谋的手段,破坏和打乱敌伏击部署,以实现反伏击的目的。     

无目标初始信息情况下舰载直升机搜索优化

根据水面舰艇编队反舰作战中舰载直升机所担负的搜索任务,基于无目标初始信息情况下的搜索问题,选取搜索面积、搜索时间和搜索距离3个指标,建立了搜索优化模型.通过仿真计算,得出了无目标初始信息情况下舰载直升机反舰作战中具体的搜索方法.其结论对于最大限度发挥现有装备的作战效能有一定的现实指导意义.     

基于区间数理论的空战目标威胁评估

针对空战目标威胁评估问题,提出了一种新的基于区间数理论的评估方法。在分析了现有的目标威胁评估方法中距离威胁模型存在不足的基础上,提出了改进的距离威胁模型。给出了区间数特征向量法求解威胁指标权重的计算步骤,建立了基于区间数理论的空战目标威胁评估的数学模型。最后给出了仿真算例,仿真结果表明该方法是合理和有效的。